Bleach - S1: Episode 3
The Older Brother's Wish, the Younger Sister's Wish
Orihime and her friend Tasuki are being attacked by a Hollow who was once Orihime’s brother. Ichigo shows up and begins fighting with him. Orihime’s brother is also struggling to gain control. Orihime is almost killed but her soul remains attached to her chain. Finally Orihime’s brother gains control long enough to say one last goodbye to his sister before Ichigo sends his soul off to the Soul Society.